The Mercury Cell
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The Mercury Cell
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SOLVED:A mercury battery uses the following electrode half-reactions: HgO(s) H2 O(l) 2 e^- ⟶Hg(l) 2 OH^-(a q) E^∘=0.098 V ZnO(s) H2 O(l) 2 e^- ⟶Zn(s) 2 OH^-(a q) E^∘=-1.260 V (a) Write a balanced equation for the overall cell reaction. (b) Calculate ΔG^∘( in kilojoules) and K at 25^∘ C for the cell . reaction. (c) What is the effect on the cell voltage of a tenfold change in the concentration of KOH in the electrolyte? Explain.
SOLVED:A mercury battery uses the following electrode half-reactions: HgO(s) H2 O(l) 2 e^- ⟶Hg(l) 2 OH^-(a q) E^∘=0.098 V ZnO(s) H2 O(l) 2 e^- ⟶Zn(s) 2 OH^-(a q) E^∘=-1.260 V (a) Write a balanced equation for the overall cell reaction. (b) Calculate ΔG^∘( in kilojoules) and K at 25^∘ C for the cell . reaction. (c) What is the effect on the cell voltage of a tenfold change in the concentration of KOH in the electrolyte? Explain.
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